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Reduction of graphene oxide nanosheets by natural beta carotene and its potential use as supercapacitor electrode

机译:天然β-胡萝卜素对氧化石墨烯纳米片的还原及其作为超级电容器电极的潜在用途

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摘要

A green, non-toxic and eco-friendly approach for the reduction of graphene oxide (GO) nanosheets using natural b-carotene is reported. The FTIR spectroscopy and thermogravimetric analyses reveal the oxygen scavenging property of b-carotene successfully removes oxygen functionalities on GO nanosheets. Complete GO reduction is achieved within 16 h with 10 mM b-carotene as\udconfirmed by the UV spectroscopy results. The high resolution transmission electron microscopy images provide clear evidence for the formation of few layers of graphene nanosheets. Furthermore,the mechanism of GO reduction by b-carotene has been proposed in this study. The electrochemical testing shows good charge storage properties of b-carotene reduced GO (142 F/g at 10 mV/s; 149 F/g at 1 A/g in Na2SO4), with stable cycling (89%) for up to 1000 cycles. The findings suggest the reduction\udof GO nanosheets by b-carotene is a suitable approach in producing graphene nanosheets for supercapacitor electrode
机译:报道了一种绿色,无毒且环保的方法,可使用天然β-胡萝卜素还原氧化石墨烯(GO)纳米片。 FTIR光谱和热重分析表明,β-胡萝卜素的除氧性能成功去除了GO纳米片上的氧官能团。如紫外光谱结果所证实,用10 mM的β-胡萝卜素可在16小时内完全还原GO。高分辨率透射电子显微镜图像为形成几层石墨烯纳米片提供了清晰的证据。此外,本研究提出了β-胡萝卜素还原GO的机理。电化学测试表明,β-胡萝卜素还原的GO具有良好的电荷存储性能(在10 mV / s下为142 F / g;在Na2SO4中为1 A / g时为149 F / g),并具有稳定的循环(89%),最多循环1000次。研究结果表明,β-胡萝卜素还原GO纳米片是生产超级电容器电极石墨烯纳米片的合适方法。

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